2016

27.04.2017 02:39

Reactive adsorption of toxic organophosphates parathion methyl and DMMP on nanostructured Ti/Ce oxides and their composites, Henych, J., Janoš, P., Kormunda, M., Tolasz, J., Štengl, V., Arabian Journal of Chemistry, 2016,

  Pure titanium and cerium oxides and their composites were prepared by the modified method of homogeneous hydrolysis with urea as the precipitating agent. The as-synthesized nanostructured oxides were examined by XRD, XPS, microscopic techniques (SEM, HRTEM), nitrogen...
27.04.2017 02:33

Polakova, L., H. Benes, P. Ecorchard, E. Pavlova, Z. Sedlakova, J. Kredatusova and V. Stengl (2016). "Nanocomposite preparation via in situ polymerization of quaternary ammonium salt ion-bonded to graphite platelets." Rsc Advances 6(1): 353-357.

Here we report a novel method of intercalation of a quaternary ammonium salt bearing a polymerizable group in between graphite galleries. By the exfoliation of the intercalate during its subsequent polymerization with n-butyl methacrylate, a polymer membrane with homogenously dispersed graphene...
27.04.2017 02:24

Mileva, A., G. Issa, J. Henych, V. Stengl, D. Kovacheva and T. Tsoncheva (2016). "Effect of preparation procedure on the formation of nanosized mesoporous TiO2-CeO2 catalysts for ethyl acetate total oxidation and methanol decomposition." Bulgarian Chemica

Two series TiO2-CeO2 samples were synthesized using homogeneous precipitation with urea and template-assisted hydrothermal procedures. The samples were characterized by nitrogen physisorption, XRD, UV-Vis, Raman and TPR techniques. The catalytic properties of the obtained materials were studied in...
27.04.2017 02:17

Janos, P., J. Henych, O. Pelant, V. Pilarova, L. Vrtoch, M. Kormunda, K. Mazanec and V. Stengl (2016). "Cerium oxide for the destruction of chemical warfare agents: A comparison of synthetic routes." Journal of Hazardous Materials 304: 259-268.

Four different synthetic routes were used to prepare active forms of cerium oxide that are capable of destroying toxic organophosphates: a sol-gel process (via a citrate precursor), homogeneous hydrolysis and a precipitation/calcination procedure (via carbonate and oxalate precursors). The samples...
27.04.2017 02:09

Tsoncheva, T., R. Ivanova, J. Henych, N. Velinov, M. Kormunda, M. Dimitrov, D. Paneva, M. Slusna, I. Mitov and V. Stengl (2016). "Iron modified titanium-hafnium binary oxides as catalysts in total oxidation of ethyl acetate." Catalysis Communications 81:

Multicomponent iron-titanium-hafnium oxide materials with different compositions were prepared by combination of homogeneous precipitation with urea and incipient wetness impregnation techniques and tested as catalysts for ethyl acetate oxidation as representative VOCs. Nitrogen physisorption, XRD,...
27.04.2017 02:02

Tsoncheva, T., R. Ivanova, M. Dimitrov, D. Paneva, D. Kovacheva, J. Henych, P. Vomacka, M. Kormunda, N. Velinov, I. Mitov and V. Stengl (2016). "Template-assisted hydrothermally synthesized iron-titanium binary oxides and their application as catalysts fo

Iron-titanium binary oxides were synthesized by template-assisted hydrothermal method. The effect of the variation in the Fe/Ti ratio and the temperature of hydrothermal treatment on the phase composition, structural, textural and redox characteristics of thus obtained materials was studied by...
27.04.2017 01:44

St'astny, M., V. Stengl, J. Henych, J. Tolasz, P. Vomacka and J. Ederer (2016). "Mesoporous manganese oxide for the degradation of organophosphates pesticides." Journal of Materials Science 51(5): 2634-2642.

Manganese(IV) oxide used for degradation of toxic organophosphorus compounds was prepared by homogeneous hydrolysis of potassium permanganate (KMnO4) with 2-chloroacetamide. The prepared sample was characterized by X-ray diffraction, scanning electron microscopy, high-resolution transmission...
27.04.2017 01:36

Pospechova, J., V. Brynych, V. Stengl, J. Tolasz, J. H. Langecker, M. Bubenikova and L. Szatmary (2016). "Polysaccharide biopolymers modified with titanium or nickel nanoparticles for removal of radionuclides from aqueous solutions." Journal of Radioanaly

New composite nanomaterials of cellulose, chitin, and chitosan modified with titanium or nickel nanoparticles were developed and tested for removal of Cs-137, Sr-85, Co-60, and Eu152+154 from aqueous solutions. The composite nanomaterials were characterized by X-ray diffraction, high-resolution...
07.12.2016 11:56

Ederer, J., P. Janos, P. Ecorchard, V. Stengl, Z. Belcicka, M. St'astny, O. Pop-Georgievski and V. Dohnal (2016). "Quantitative determination of acidic groups in functionalized graphene by direct titration." Reactive & Functional Polymers 103: 44-53.

Abstract Direct titration with NaOH was used to quantify the acidic functional group content in graphene oxide (Go). Three different methods were used to evaluate the experimental data: the first derivation of the titration curve, Gran linearization and an empirical approach suggested by...
07.12.2016 11:32

Dimitrov, M., R. Ivanova, N. Velinov, J. Henych, M. Slušná, V. Štengl, J. Tolasz, I. Mitov and T. Tsoncheva (2016). "Mesoporous TiO2 powders as host matrices for iron nanoparticles. Effect of the preparation procedure and doping with Hf." Nano-Structures

  Abstract The aim of the current investigation is to follow the formation of iron phase in mesoporous nanocrystalline titania and Hf-doped titania powders and its influence on the physicochemical and catalytic properties of the obtained materials. The parent host matrices were synthesized by...

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Kontakt

Mgr.Václav Štengl, Ph.D., DSc. Ústav anorganické chemie AV ČR v.v.i.
250 68 Husinec-Řež
266 172 202